Electrochemical Sensing Characteristics of 3D TiO₂ Nanostructures with Different Crystal Structures and Morphologies

Three-dimensional (3D) metal inorganics have gained tremendous interests for a series of applications. Here, we prepared TiO 2 microspheres, urchin-like TiO 2 , and flower-like TiO 2 by hydrothermal method. The morphologies of the three 3D TiO 2 nanostructures were characterized by scanning electron microscopy and X-ray diffraction analyses. The electrochemical behaviors of the 3D TiO 2 nanostructures were investigated by electrochemical impedance spectroscopy and cyclic voltammetry studies. Results showed that 3D TiO 2 -modified electrodes exhibited improved electrochemical performance compared with bare electrode. The three 3D nanostructures were then used with a modified glassy carbon electrode to detect dopamine (DA). According to the experimental results, the flower-like TiO 2 /GCE demonstrated excellent electrochemical performance than the two other electrodes. The enhanced electrochemical performance of the 3D flower-like TiO 2 /GCE is mainly affected by the structure of anatase crystal, which is the most important factor for the enhanced electrochemical performances toward DA detection. The flower-like TiO 2 /GCE, urchin-like TiO 2 /GCE, and TiO 2 microspheres/GCE possessed linear ranges of 0.02–160, 1–180, and 1–160 μM, with limit of detection values of 0.007, 0.31, and 0.33 μM, respectively.