Doolittle's law relates a kinetic property such as viscosity or dielectric relaxation to the free volume. In nematogens the volume expansion is discontinuous at the nematic-isotropic transition temperature Tc and nonlinear at (Tc-20 K)T<~Tc. This makes a test of Doolittle's law possible.
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H. R. Zeller (1982) studied this question.
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