A twisted six-membered Al2N4 ring, which is rationalized by ab initio calculations, is present in compound 1. This compound together with 2 is obtained from the reaction of acetylenes with an aluminum dihydride bearing pyrazolato ligands. Compounds 1 and 2 are the first structurally characterized aluminum compounds with terminal acetylide groups.
No takes yet. Share an insight, caveat, or question.
Zheng et al. (2000) studied this question.
Synapse has enriched 4 closely related papers on similar clinical questions. Consider them for comparative context: