January 1, 2000Chemical Communications59 citations
Homogeneously catalyzed, chelate assisted hydrogenolysis of an amine C–N bond
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Abstract
Reaction of RhCl(COE)22 with an excess of the aromatic aminophosphine 1-(diethylaminomethyl)-3-(di-tert-butylphosphinomethyl)-2,4,6-tri methylbenzene (2) in dioxane under mild H2 pressure results in selective catalytic activation of an unstrained C–N single bond.
Cite This Study
Gandelman et al. (2000) studied this question.