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The allylation and deuteration of six‐membered cyclic sulfinylated radicals were investigated. For this purpose, radicals with the predefined conformations I and II were generated from 2‐(phenylselenenyl)thiacyclo‐hexane‐1‐oxide derivatives 7–10 ( Scheme ). Steric effects were insufficient to account for all the observed selectivities. The participation of stereoelectronic effects are envisaged to explain the stereoselective axial deuteration of type‐ II radicals.
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Philippe Rehaud (1991) studied this question.
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