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A base‐promoted three‐component coupling of carbon dioxide, amines, and N ‐tosylhydrazones has been developed. The reaction is suggested to proceed via a carbocation intermediate and constitutes an efficient and versatile approach for the synthesis of a wide range of organic carbamates. The advantages of this method include the use of readily available substrates, excellent functional group tolerance, wide substrate scope, and a facile work‐up procedure.
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Xiong et al. (2015) studied this question.
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