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We describe a reptation model applicable to long-chain polyelectrolytes, like DNA in a gel, and derive an exactly solvable master equation for the probability distribution of the chain's extension in an applied electric field. The effect on the steady-state mobility of reduced charge at the chain's ends is studied, and differences between the model's steady-state probability distributions and ones derived from counting chain configurations are noted.
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Lumpkin et al. (1989) studied this question.
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