Ion Pairing Limits Crystal Growth in Metal–Oxygen Batteries

Aprotic alkali metal–oxygen batteries are promising high specific energy alternatives to Li-ion batteries. Growth and dissolution of alkali metal oxides such as Li 2 O 2 in Li–O 2 batteries and NaO 2 and KO 2 in Na–O 2 and K–O 2 batteries, respectively, are central to the discharge and charge processes in these batteries. However, crystal growth and dissolution of the discharge products is poorly understood, especially in aprotic electrolytes. In this work, we chose the growth of NaO 2 in Na–O 2 batteries as a model system and show a strong correlation between the electrolyte salt concentration and the NaO 2 crystal size. With a combination of experiments and theory, we argue that the correlation is a direct manifestation of the strong cation–anion interactions, leading to decreased crystal growth rate at high salt concentrations. Furthermore, we propose and experimentally demonstrate that cation-coordinating crown molecules are electrochemically stable electrolyte additives that weaken ion pairing and enhance discharge capacities in metal–oxygen batteries.