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An analysis starting from Hund’s case d has been used to extend the work of Herzberg and Jungen on the 5g→4f emissions in H2. A simple analytical expression for the line intensities is presented that agrees with their calculations is about 1%. All of the experimentally observed lines have been accounted for by including higher vibrational levels in our calculations.
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Chang et al. (1984) studied this question.
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