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August 19, 2026Canadian Metallurgical Quarterly

Effects of chlorides and sulphates on molten salt hot corrosion of dissimilar welded joints of 70 MW circulating fluidised bed combustion power plant super-heaters tubes

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Authors

SPS. Senthur PrabuRKRoyal George KurissuveettilRCRajendran Chinnasamy

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Overview

Experimental study reveals superior hot corrosion resistance in weld metal compared to P22 base steel under molten salt exposure, highlighting methods to improve power plant tube durability.

Key Points

  • Investigate the hot corrosion behavior, oxide scale evolution, and degradation mechanisms of dissimilar welded joints between P91 and P22 steels in a high-temperature molten salt environment.
  • Fabricated dissimilar joints between SA335 P91 and SA218 P22 steels using pulsed current gas tungsten arc welding (PCGTAW) with E70S-2 filler metal.
  • Exposed the welded samples to a molten salt mixture (K2SO4 + NaCl) at 700 ± 2°C across 50 thermal cycles.
  • Evaluated corrosion kinetics, phase evolution, and microstructural degradation using scanning electron microscopy, thermogravimetric analysis, X-ray diffraction, and energy-dispersive spectroscopy.
  • The weld metal exhibited superior hot-corrosion resistance due to the formation of a dense, protective Cr2O3-rich oxide scale.
  • The P22 base steel region experienced localized hot corrosion attack accompanied by significant oxide scale spallation during thermal cycling.

Cite This Study

Prabu et al. (2026) studied this question.

synapsesocial.com/papers/6a85643903308d306e2d7dechttps://doi.org/10.1080/00084433.2026.2717668
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