Measurement of Water Diffusivities in Barley Components Using Diffusion Weighted Imaging and Validation with a Drying Model

Diffusion-weighted magnetic resonance imaging was used to determine water diffusion coefficients (D) in hull-less barley kernel components (endosperm and embryo) at 20.5±0.5°C. The D values in barley components were time-dependent and restricted in nature as indicated by the decrease in the apparent diffusion coefficient with increasing diffusion time (from 3 to 25 ms). A four-parameter Padé approximation model was used to estimate D and pore geometry (pore surface area–to-volume ratio, pore size, porosity, electrical conductivity and permeability of water) of the barley components after long diffusion time (t → ∞) using data obtained during a relatively short period of diffusion. The D of embryo and endosperm were 2.2±0.07 × 10−5 mm 2 Czuchajowska , Z. ; Klamczynski , A. ; Paszczynska , B. ; Baik , B.-K. Structure and functionality of barley starches . Cereal Chemistry 1998 , 75 ( 5 ), 747 – 754 .[Crossref] , [Google Scholar]/s and 1.0±0.10 × 10−5 mm 2 Czuchajowska , Z. ; Klamczynski , A. ; Paszczynska , B. ; Baik , B.-K. Structure and functionality of barley starches . Cereal Chemistry 1998 , 75 ( 5 ), 747 – 754 .[Crossref] , [Google Scholar]/s, respectively. These D values were used to simulate moisture and temperature patterns during the drying of a barley kernel using a two-dimensional simultaneous heat and moisture transfer model and compared with literature D values for validation purposes. Based on the comparison, the D values of barley components obtained from our study can be used to develop realistic models of water transport in barley during different postharvest processing operations (e.g., drying, kilning, steeping).