What question did this study set out to answer?

To synthesize, isolate, and structurally characterize novel platinum complexes coordinated to reactive seven-membered ring ligands, specifically cycloheptatrienylidene and cycloheptatetraene.

April 1, 1993Organometallics

Platinum complexes of cycloheptatrienylidene and cycloheptatetraene

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Authors

ZLZheng LuHuazhong Agricultural University WJW. M. JonesJohnson & Johnson (United States)WWWilliam R. WinchesterGrand Valley State University

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Implication

Chemical synthesis demonstrates stable platinum complexes with cycloheptatrienylidene and cycloheptatetraene, highlighting novel coordination modes of strained carbocycles.

Key Points

To synthesize, isolate, and structurally characterize novel platinum complexes coordinated to reactive seven-membered ring ligands, specifically cycloheptatrienylidene and cycloheptatetraene.
Generated reactive seven-membered carbocyclic precursors and reacted them with platinum metal centers.
Characterized the resulting coordination complexes and evaluated the bonding interactions between platinum and the unsaturated carbon rings.
Successfully coordinated and stabilized transient cycloheptatrienylidene and cycloheptatetraene species within platinum coordination spheres.
Identified distinct structural and electronic ligand configurations stabilized through direct platinum backbonding.

Cite This Study

Lu et al. (1993) studied this question.

synapsesocial.com/papers/6a8573d64fe931a6e65e2265 https://doi.org/10.1021/om00028a058

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Implication

Chemical synthesis demonstrates stable platinum complexes with cycloheptatrienylidene and cycloheptatetraene, highlighting novel coordination modes of strained carbocycles.

Platinum complexes of cycloheptatrienylidene and cycloheptatetraene

Discussion

Member takes

Implication

Key Points

Cite This Study

Platinum complexes of cycloheptatrienylidene and cycloheptatetraene

Discussion

Member takes

Implication

Key Points

Cite This Study

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