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Radical processes explain the reactivity and selectivity observed in a one-pot, two- or three-component domino reaction, which consists of 1,4-addition, carbocyclization, and quenching with electrophiles. This radical–polar crossover reaction leads stereoselectively to 3,4-disubstituted 3-methoxycarbonylpyrrolidines (see scheme).
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Dénès et al. (2003) studied this question.
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