What question did this study set out to answer?

Compare the reaction pathways, transition states, and stereochemical control mechanisms between catalytic intramolecular hydroacylation and hydrosilation.

August 1, 1998Accounts of Chemical Research

Asymmetric Catalysis. A Comparative Study of the Mechanisms of Intramolecular Hydroacylation and Hydrosilation

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Authors

BBB. BosnichUniversity of Chicago

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Implication

Mechanistic review compares catalytic pathways of intramolecular hydroacylation and hydrosilation, highlighting principles governing stereoselectivity and transition states.

Key Points

Compare the reaction pathways, transition states, and stereochemical control mechanisms between catalytic intramolecular hydroacylation and hydrosilation.
Comparative mechanistic analysis of transition-metal-catalyzed intramolecular hydroacylation and hydrosilation reactions.
Evaluation of molecular structures and catalyst-substrate transition states governing asymmetric induction and stereoselectivity.
Delineates distinct mechanistic steps and intermediate pathways differentiating intramolecular hydroacylation from hydrosilation catalytic cycles.
Identifies the key molecular interactions and transition-state geometries responsible for stereoselectivity and enantiomeric control in both reaction classes.

Cite This Study

B. Bosnich (1998) studied this question.

synapsesocial.com/papers/6a8592f5d06b31cc19d0cb16 https://doi.org/10.1021/ar970095i

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Implication

Mechanistic review compares catalytic pathways of intramolecular hydroacylation and hydrosilation, highlighting principles governing stereoselectivity and transition states.

Asymmetric Catalysis. A Comparative Study of the Mechanisms of Intramolecular Hydroacylation and Hydrosilation

Discussion

Member takes

Implication

Key Points

Cite This Study

Asymmetric Catalysis. A Comparative Study of the Mechanisms of Intramolecular Hydroacylation and Hydrosilation

Discussion

Member takes

Implication

Key Points

Cite This Study

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