The alkaline hydrolysis of some dialkyl p ‐nitrophenyl phosphates (RO) 2 P(O)OC 6 H 4 NO 2 , where R = methyl, ethyl, n ‐propyl, iso propyl, n ‐butyl, iso butyl and sec ‐butyl is described. The effects of α‐, β‐ and γ‐substitution on reactivity as expressed in ΔH* and ΔS* are discussed.
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Ginjaar et al. (1958) studied this question.
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