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Silver(I) and palladium(II) complexes of new chiral N-heterocyclic carbene (NHC)−imine ligands derived from trans -1,2-diaminocyclohexane have been prepared. These ligands have been applied to a palladium(II)-catalyzed asymmetric allylic alkylation reaction giving a maximum ee of 92%.
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Bonnet et al. (2003) studied this question.
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