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A nanoscale slipped sandwich of Tb(10) is formed from the reaction of 5-bromo-3-methoxysalicylaldehyde (HL) with TbCl(3)x6H(2)O and Zn(OAc)(2)x2H(2)O. The compound also features an unusual example of a coordinated methylhemiacetal which is derived from HL.
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Yang et al. (2004) studied this question.
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