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Mixed valence complexes containing ferro- and ferricyanide have been known for almost 300 years, but no dinuclear, non-polymeric examples of these complexes have been structurally characterized. Here we report the first such example, comprising ferrocyanide coordinated to a pentaaminecobalt(III) complex. This FeII−CoIII complex may be reversibly oxidized to the FeIII−CoIII analogue.
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Bernhardt et al. (1999) studied this question.
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