A cobalt( ii ) coordination polymer-derived catalyst engineered via temperature-induced semi-reversible single-crystal-to-single-crystal (SCSC) dehydration for efficient liquid-phase epoxidation of olefins

) as the final oxidant in the presence of the sacrificial i-butyraldehyde (IBA) reductant. For using the dihydrous phase 2, cyclohexene and various other olefins were catalytically oxidised to their corresponding epoxides with up to 38.5% conversion and 99.0% selectivity. The catalyst 2 can be expediently recycled in four runs without significant loss of activity. This research demonstrates that a little innovation in the active-site-engineered organic-inorganic hybrid materials can significantly enhance the catalytic performance and selectivity of coordination polymer-derived heterogeneous catalysts.