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A microscopic theory of phase transition in the protonic superionic conductors is proposed. By taking into account short‐range proton correlations on hydrogen bonds a order‐disorder Slater‐type phase transition of first order is obtained. Due to the linear coupling between the order parameter and lattice deformation the phase transition is ferroelastic with a soft elastic coefficient C 11 ‐ C 12 .
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Н. М. Плакида (1986) studied this question.
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