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August 20, 2026Advanced Functional MaterialsOpen Access

Roll‐to‐Roll Processable EC/TC Hybrid Smart Windows Driven by a Bidirectional Dual‐Chromic Polymer Electrolyte

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Authors

SKSoyeon KimEJEuiseok JeongMJMuhammad Jahandar

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Overview

Materials study demonstrates roll-to-roll hybrid electrochromic and thermochromic smart windows, indicating a scalable pathway for energy-efficient building temperature control.

Key Points

  • To develop a scalable, large-area hybrid smart window combining electrochromic and thermochromic functions using a bidirectional dual-chromic polymer electrolyte.
  • Synthesized a dual-chromic polymer electrolyte (DCPE) blended with hydroxypropyl methylcellulose (HPMC) to suppress water loss and stabilize thermal cycling.
  • Optimized the ion storage layer to enhance electrochromic charge capacity and coloration efficiency.
  • Fabricated large-scale (up to 750 × 600 mm) PEDOT:PSS and WO3 films using continuous roll-to-roll (R2R) coating and evaluated thermal performance under simulated IR and outdoor conditions.
  • The hybrid system achieved a coloration efficiency of 308.65 cm² C⁻¹ and expanded solar modulation (ΔT_sol) from 15.18% under electrochromic-only mode to 43.09% under dual electrochromic/thermochromic activation.
  • The films demonstrated operational durability exceeding 200 thermochromic cycles and 10,000 electrochromic cycles with switching times under 90 seconds.
  • Large-area (750 × 600 mm) devices lowered indoor temperatures by 10–14°C with a thermal shielding efficiency (η_thermal) of 50–80%.

Cite This Study

Kim et al. (2026) studied this question.

synapsesocial.com/papers/6a86b5ff8a91293e6a1cd945https://doi.org/10.1002/adfm.77765
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