The limitation on the validity of the impact theory formula has the consequence that the shift in the vibration-rotation transition (1–0, 2–0 bands, P and R branches) lines of HCl due to the pressure of noble gases is j dependent. For high j there is a constant limit shift. For the light noble gases agreement with the data may be reached by taking into account a repulsive potential due to overlap.
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R. Englman (1962) studied this question.
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