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The energy separation S between the 2²S1/2 and 2²P1/2 states of singly ionized helium was measured using a microwave method. Helium atoms in the space between the plates of a spherical-mirror Fabry-Perot resonator are bombarded continuously by electrons of 200-eV energy to produce helium ions in the 2²S1/2 metastable state. The applied modulated rf power induces transitions in the metastable ions to the short-lived 2²P1/2 state. The 40.8-eV photons emitted by the decay of the 2²P1/2 ions to the ionic ground state 1²S1/2 are quantum converted to visible photons by a scintillator and are then guided to a photomultiplier. The output of the photomultiplier is detected and amplified synchronously with the rf power. The experiment made use of the Zeeman effect of the fine structure and is performed in an applied homogeneous magnetic field. Three different operating values for the helium pressure are used and the result is extrapolated to a zero-pressure value. A through search was made for all possible systematic errors in the experiment. The value for S thus obtained is 14 046.2 ±{} 2.0 MHz. The quoted uncertainty consists of three standard deviations for the statistical error plus estimates of systematic errors. This result agrees with the previous experimental values for S (within three standard deviations), and with the latest theoretical value of 14 044.5 ±{} 5.2 MHz.
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Narasimham et al. (1971) studied this question.
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