Enhanced surface metallic density of states in icosahedral quasicrystals

Valence and core-level photoemission spectra show that cleaved i-Al-Pd-Mn quasicrystals have a pronounced metallic signature. Spectra from states above EF, populated by increasing the sample temperature, indicate the presence of a shallow pseudogap 0.09 eV above EF. The Al $2p$ line asymmetry, on the other hand, which indicates metallic behavior, decreases with increasing photoelectron escape depth. This implies a decreasing density of states at EF with increasing distance from the surface, consistent with indications that the density of states near EF in the bulk is reduced. Our results thus help to resolve the apparent contradiction between the theoretical predictions for a bulk pseudogap, and the clear metallic Fermi edges in photoemission.