Si2pCore-Level Spectroscopy of the Si(111)-(1 × 1):H and Si(111)-(1 × 1):D Surfaces: Vibrational Effects and Phonon Broadening

Very sharp photoemission spectra have been obtained from the Si(111)-(1 ×{} 1):H and Si(111)-(1 ×{} 1):D surfaces prepared by a simple well-defined in situ method. Both the Si $2p$ core-level spectra and the valence band spectra are essentially identical to spectra reported for the chemically prepared (1 ×{} 1):H surface. We can conclusively exclude contributions from Si-H(D) stretching vibrational losses to the Si $2p$ core-level spectra, contrary to a recent suggestion. The line shape of the component originating from the surface Si atoms is found to be asymmetric, which we assign to asymmetric phonon broadening.