Exceptional Electronic Modulation of Porphyrins through meso-Arylethynyl Groups. Electronic Spectroscopy, Electronic Structure, and Electrochemistry of 5,15-Bis[(aryl)ethynyl- 10,20-diphenylporphinato]zinc(II) Complexes. X-ray Crystal Structures of 5,15-Bis[(4‘-fluorophenyl)ethynyl- 10,20-diphenylporphinato]zinc(II) and 5,15-Bis(4‘-methoxyphenyl)ethynyl-10,20-diphenylporphyrin