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The reaction of silver azide with triphenylsulfonium or tetraphenylphosphonium azide results in the formation of the binary silver-nitrogen compound, the novel diazido-argentate(I) anion [Ag(N(3))(2)](-). The crystal structures of both salts of this anion show different cation dependent azide coordination spheres around silver.
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Klapötke et al. (2008) studied this question.
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