Blended polyelectrolyte multilayer films that include a hydrogen-bonding constituent have been used as templates for the preparation of nanoporous polymer thin films. By crosslinking the electrostatic components following layer-by-layer (LbL) deposition and removing the hydrogen-bonding component by pH elevation (see Figure), nanopores in the range 10–50 nm are formed.
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Li et al. (2005) studied this question.
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