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A series of three bis-tridentate bridging ligands has been prepared in which two 1,10-phenanthroline units have been symmetrically appended to a central pyridazine, pyrimidine, or pyrazine ring. These ligands have been treated with [Ru(tpy-d(11))Cl(3)] to afford both mono- and bimetallic complexes that show very self-consistent NMR properties. [structure: see text]
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Brown et al. (2002) studied this question.
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