The infrared spectrum of methyl chloroform has been investigated in the region 1.6μ—20μ with a Perkin-Elmer spectrometer using LiF, NaCl, and KBr prisms. Vibrational assignments are given to all the bands observed, and all fundamentals except the torsional vibration have been fairly definitely established. Most of the bands, whether perpendicular or parallel type, show the same kind of PQR structure.
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Putcha Venkateswarlu (1951) studied this question.
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