The kinetics of the transfer of the nitroso group from N -methyl- N -nitroso- p -toluenesulfonamide to secondary alkylamines (dimethylamine, methylethylamine, methylbutylamine, methylhexylamine, methyloctylamine, and methyldodecylamine) was studied using a wide variety of water/AOT/isooctane microemulsions as reaction media. The diverse kinetic behavior of these amines can be explained quantitatively on the basis of a single model, taking into account the distribution of the amine between the aqueous and isooctane phases and their mutual interface (surfactant film); the reaction always takes place at the surfactant film. The reactivities of the amines are discussed in comparison with the reactivity observed in water.
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García‐Río et al. (2003) studied this question.
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