Plasticization of the polycarbonate of bisphenol A ( 1 ) by dibutyl 4,4′‐ethylenedibenzoate ( 2 ) and dibutyl 4,4′‐stilbenedicarboxylate ( 3 ) was studied in order to establish the influence of the molecular rigidity on the antiplasticization phenomenon. UV spectroscopy, dielectric and mechanical properties proved that a rigid trans‐configuration of the “plasticizer” molecules and a strong interaction enhance antiplasticization.
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Суворова et al. (1990) studied this question.
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