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We report the results of electron transmission experiments in the chlorofluoromethanes and CCl 4 in the energy range from less than 10 meV to a few hundred meV, using a magnetically confined electron beam, generated from a high resolution, synchrotron photoionization source on SuperACO, LURE. Scattering spectra show evidence of electron attachment, Ramsauer-Townsend effects, and pure rotational and rovibrational inelastic scattering. For CF 3 Cl and CF 2 Cl 2 we analyse the inelastic scattering phenomena in terms of the first Born approximation, showing that this gives a good fit to the form of the variation of the pure rotationally inelastic cross section with electron kinetic energy.
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Randell et al. (1993) studied this question.
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