Self-ENDOR measurements for the 51V isotope of double-positive vanadium in silicon are presented. The spin-Hamiltonian parameters have been determined. For an adequate description of the spectrum it was necessary to include a higher-order hyperfine term of the type S3I in the Hamiltonian. Existing theories do not account in a satisfactory way for the magnitude of the S3I term.
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Kooten et al. (1987) studied this question.
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