First Unequivocal Observation of the Whole Bell-Shaped Energy Gap Law in Intramolecular Charge Separation from S₂Excited State of Directly Linked Porphyrin−Imide Dyads and Its Solvent-Polarity Dependencies

ADVERTISEMENT RETURN TO ISSUEPREVCommunicationNEXTFirst Unequivocal Observation of the Whole Bell-Shaped Energy Gap Law in Intramolecular Charge Separation from S2 Excited State of Directly Linked Porphyrin−Imide Dyads and Its Solvent-Polarity DependenciesNoboru Mataga, Haik Chosrowjan, Yutaka Shibata, Naoya Yoshida, Atsuhiro Osuka, Takeshi Kikuzawa, and Tadashi OkadaView Author Information Institute for Laser Technology, Utsubo-Hommachi 1-8-4 Nishi-ku, Osaka 550−0004, Japan Department of Chemistry, Graduate School of Science Kyoto University, Kyoto, 606-8502, Japan Department of Chemistry, Faculty of Engineering Science Osaka University, Toyonaka, 560-8531, Japan Cite this: J. Am. Chem. Soc. 2001, 123, 49, 12422–12423Publication Date (Web):November 16, 2001Publication History Received3 April 2001Published online16 November 2001Published inissue 1 December 2001https://pubs.acs.org/doi/10.1021/ja010865shttps://doi.org/10.1021/ja010865srapid-communicationACS PublicationsCopyright © 2001 American Chemical SocietyRequest reuse permissionsArticle Views715Altmetric-Citations96LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-AlertscloseSupporting Info (1)»Supporting Information Supporting Information SUBJECTS:Charge transfer,Energy,Fluorescence,Solvation dynamics,Solvents Get e-Alerts