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A radical transformation of the type Trṗ‐TyrOH → TrpH‐TyrȮ, previously observed by pulse radiolysis, has been detected following 265 nm laser excitation of oxygen saturated neutral aqueous solutions of TrpH‐TyrOH, TyrOH‐TrpH and cyclo‐TrpH‐TyrOH. A similar process was observed after photoexcitation of the proteins α‐lactalbumin and α‐chymotrypsin.
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Sloper et al. (1980) studied this question.
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