Apparatus and techniques are described for the titration of acids and bases by constant-current coulometry. The precision and accuracy of the method are indicated by titrations of benzoic acid, potassium acid phthalate, adipic acid, hydrochloric acid, and sodium carbonate. Standard deviations of ±0.003 percent have been obtained which indicate that the reliability of the method is equal to or exceeds that of classical analytical procedures.
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Taylor et al. (1959) studied this question.