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The two in situ 2 + 3 intermolecular cycloaddition reactions between inorganic complexes bis(3-cyanopyrdine)copper(II)azide ( A ) offer homometallic and heterometallic 3D novel tetrazole coordination polymers, (3-C 5 H 4 N-CN 4 ) 2 Cu(I) 2 ( 1 ) and (3-C 5 H 4 N-CN 4 )Cu(I)Cd(II)Cl 2 ( 2 ), respectively, in the presence of Lewis acid CuCl 2 and CdCl 2 in which A is used to replace the organic cyano group and NaN 3 during Sharplessʼs tetrazole synthesis. Their interesting luminescent properties are reported.
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Tang et al. (2007) studied this question.
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