Transamination of the amidosamarium complex [{(Me3Si)2N}2Sm(tmeda)] with octaethylporphyrinogen (OEPG-H4) gives the dinuclear complex [(OEPG)Sm2(Et2O)2], which has two SmII centers and a short Sm–Sm contact. (In the structure shown on the right the Et2O ligands are omitted for clarity.)
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Song et al. (1995) studied this question.
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