Hydrate formation conditions of hydrogen + hydrocarbon gas mixtures (H 2 + CH 4, H 2 + C 3 H 8, H 2 + CH 4 + C 3 H 8, and H 2 + CH 4 + C 2 H 6 + C 3 H 8 ) in pure water have been measured in a sapphire cell using the “pressure search” method. The experimental temperature range was (274−280) K, and the pressure-range was (0.65−7.0) MPa. The hydrogen content in the gas mixtures varies from 22 mol % to 92 mol %.
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Zhang et al. (2000) studied this question.