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Cationic aminocyclopentadienyl and hydroxycyclopentadienyl ruthenium alcohol complexes were synthesized from reaction of the corresponding ruthenium chloride with AgBF 4 in the presence of an alcohol. Exchange rates of free alcohol with hydroxycyclopentadienyl and aminocyclopentadienyl ruthenium benzyl alcohol complexes were rapid ( t 1/2 = 5−10 min) at −47 °C.
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Casey et al. (2003) studied this question.
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