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We present results from a diffusion study of polymer chains in thin films, in which the mobility of chains labeled with a fluorescent dye in a matrix of unlabeled chains has been measured using fluorescence recovery after patterned photobleaching. The results presented here indicate that there is a substantial decrease in the lateral diffusion coefficient for films thinner than ∼1500 Å.
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Frank et al. (1996) studied this question.
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