Previous theoretical treatments of the thermodynamics of high-polymer solutions have assumed that the entropy of mixing is independent of the magnitude of the heat of mixing. The present treatment considers energy interactions on a molecular scale and includes these in the configurational partition function. This leads to the derivation of expressions for the heat of mixing and the entropy of mixing which reflect the effect of solvent-solute interaction. One result of particular interest is an explicit expression for the temperature dependence of osmotic pressure.
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Alfrey et al. (1945) studied this question.
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