Highly efficient and selective aqueous phase hydrogenation of aryl ketones, aldehydes, furfural and levulinic acid and its ethyl ester catalyzed by phosphine oxide-decorated polymer immobilized ionic liquid-stabilized ruthenium nanoparticles

Simon Doherty; Julian G. Knight; Tom Backhouse; Tina S. T. Tran; Richard Paterson; Fredrik Ståhl; Hussam Y. Alharbi; Thomas W. Chamberlain; Richard A. Bourne; Rebecca Stones; A P Griffiths; J. P. White; Zabeada Aslam; C. Hardare; Helen Daly; Jack Hart; Robert H. Temperton; James N. O’Shea; Nicholas H. Rees

doi:10.1039/d2cy00205a

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Phosphine oxide-decorated polymer immobilized ionic liquid stabilized RuNPs catalyse the hydrogenation of aryl ketones with remarkable selectivity for the CO bond, complete hydrogenation to the cyclohexylalcohol and hydrogenation of levulinic acid to γ-valerolactone.

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Doherty et al. (2022) studied this question.

synapsesocial.com/papers/6a891344e88fc9ac761a294d https://doi.org/10.1039/d2cy00205a

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Highly efficient and selective aqueous phase hydrogenation of aryl ketones, aldehydes, furfural and levulinic acid and its ethyl ester catalyzed by phosphine oxide-decorated polymer immobilized ionic liquid-stabilized ruthenium nanoparticles

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Highly efficient and selective aqueous phase hydrogenation of aryl ketones, aldehydes, furfural and levulinic acid and its ethyl ester catalyzed by phosphine oxide-decorated polymer immobilized ionic liquid-stabilized ruthenium nanoparticles

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