An electron spin resonance spectrum, due to the formation of cupric ions during illumination, has been observed in crystals of silver chloride containing 0–1 mol %, of cuprous chloride, which have been quenched to−183[ddot]c immediately following irradiation. The spectrum fades rapidly if the crystals are kept at any temperature above −140[ddot]c after the end of illumination. An interpretation of this behaviour is given which is based upon the Mitchell theory of the photochemical process in crystals of silver halides.
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Ciccarello et al. (1960) studied this question.
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