A two-fold interpenetrated metal–organic framework (MOF), [(Zn4O)2L4(DMF)2(H2O)3], was prepared using the tritopic ligand 4,4′,4′′-[1,3,5-benzenetriyltris(carbonylimino)]trisbenzoic acid (H3L) and zinc nitrate. The MOF, based on the hexatopic tetranuclear Zn4O(COO)6 secondary building unit, has a (3,6)-connected network with an rtl topology and a large solvent cavity.
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Song et al. (2010) studied this question.
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