Bridging two traditional but distinct research areas—polyoxometalate chemistry and cuprous halide clusters—the (4,12)-connected 3D framework (NH4)[Cu24I10L12][PMoV2MoVI10O40]3 has been built by covalent linkage of nanoscale Keggin anions and [Cu24I10L12]14+ clusters (see picture; L is a multidentate N-heterocyclic ligand); it exhibits remarkable photoluminescent and electrochemical properties.
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Wang et al. (2006) studied this question.
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