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The efficient asymmetric hydrosilylation of ketones with a chiral titanocene catalyst has been realized. In this procedure, ( R,R )-ethylenebis(tetrahydroindenyl) titanium difluoride ( 1 ) was used as the precatalyst, and alcohol additives were employed. Aromatic and α,β-unsaturated ketones were reduced to the corresponding alcohols with a high level of enantioselectivity.
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Yun et al. (1999) studied this question.
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