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Experimental study demonstrates diimine–palladium catalyzed isomerization polymerization of methylenecyclohexanes, indicating a route to high-thermal-stability cyclic polymers.
Diimine–Pd complex promotes isomerization polymerization of methylenecyclohexane and 4-alkyl-1-methylenecyclohexanes to afford the polymers which contain trans - and cis -1,4-cyclohexylene groups, respectively, along the polymer chain. The polymerization of 3-methyl-1-methylenecyclohexane yields the polymer having trans -1,3-cyclohexylene groups. DSC measurement of a part of the polymers revealed their glass transition at high temperature ( T g = 162 and 201 °C).
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Takeuchi et al. (2015) studied this question.
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