Recently, much attention has been centered on the asymmetric reaction by the use of axially chiral biaryls as the chirality-recognizing auxiliaries, and thus, there has been an increasing interest in the construction of the requisite atropisomeric biaryl skeletons. Here we review recent progress in the field of chemistry as follows : 1) Introduction. 2) Prepararation of Axially Chiral Biaryls. 3) Diastereo Differentiating Asymmetric Reactions with Axially Chiral Biaryls. 4) Enantio Differentiating Asymmetric Reactions.
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Miyano et al. (1986) studied this question.